Understanding the Density and Properties of 2 M Potassium Permanganate (KMnO4) Solution

Summary

Potassium permanganate (KMnO4) is a widely used chemical compound in various applications, particularly in chemistry experiments and water treatment. This comprehensive guide provides a detailed overview of the density and properties of a 2 M KMnO4 solution, including its technical specifications, practical applications for physics students, and relevant formulas and examples.

Density of 2 M KMnO4 Solution

kmno4 density 2

The density of a 2 M KMnO4 solution can be calculated using the molar mass of KMnO4 and the molarity of the solution. The molar mass of KMnO4 is approximately 158.03 g/mol, and the molarity is 2 mol/L.

The density (ρ) can be calculated using the following formula:

ρ = molar mass / molarity × 1000 (g/L)
ρ = 158.03 g/mol / 2 mol/L × 1000 (g/L)
ρ ≈ 79.015 g/L

Therefore, the density of a 2 M KMnO4 solution is approximately 79.015 g/L.

Technical Specifications of 2 M KMnO4 Solution

  1. Molar Mass: The molar mass of KMnO4 is approximately 158.03 g/mol.
  2. Molarity: The molarity of the 2 M KMnO4 solution is 2 mol/L.
  3. Density: The density of the 2 M KMnO4 solution is approximately 79.015 g/L.
  4. Temperature: The density of the solution can be affected by temperature. It is recommended to use the solution at room temperature (20-25°C) for consistent density values.
  5. Preparation: To prepare a 2 M KMnO4 solution, dissolve a precise amount of KMnO4 in deionized water, ensuring that the final volume corresponds to the desired molarity.

Practical Applications for Physics Students

  1. Chemical Reactions: KMnO4 is involved in various chemical reactions, including redox reactions and titrations. Understanding its density helps calculate the amount of KMnO4 required for specific reactions.

Example: In a redox titration, the volume of a 2 M KMnO4 solution required to react with a known volume and concentration of a reducing agent can be calculated using the density of the KMnO4 solution.

  1. Solutions and Solubility: Studying the density of KMnO4 solutions can help physics students understand the concept of molarity, molality, and other concentration units.

Example: The density of a 2 M KMnO4 solution can be used to determine the mass of KMnO4 dissolved in a given volume of the solution.

  1. Safety: Knowing the density of KMnO4 solutions can help students determine the appropriate storage and handling procedures, minimizing potential hazards.

Example: The density of a 2 M KMnO4 solution can be used to calculate the weight of the solution in a container, which is important for safe transportation and storage.

Formulas and Examples

  1. Density Calculation:
    ρ = molar mass / molarity × 1000 (g/L)
    ρ = 158.03 g/mol / 2 mol/L × 1000 (g/L)
    ρ ≈ 79.015 g/L

  2. Mass of KMnO4 in a 2 M Solution:
    Given:

  3. Volume of the 2 M KMnO4 solution: 500 mL
  4. Density of the 2 M KMnO4 solution: 79.015 g/L

Mass of KMnO4 = Density × Volume
Mass of KMnO4 = 79.015 g/L × 0.5 L
Mass of KMnO4 ≈ 39.5075 g

  1. Volume of 2 M KMnO4 Solution Required for a Redox Titration:
    Given:
  2. Concentration of the reducing agent: 0.1 M
  3. Volume of the reducing agent: 25 mL
  4. Molarity of the KMnO4 solution: 2 M
  5. Density of the 2 M KMnO4 solution: 79.015 g/L

Volume of 2 M KMnO4 solution = (Concentration of reducing agent × Volume of reducing agent) / Molarity of KMnO4 solution
Volume of 2 M KMnO4 solution = (0.1 M × 0.025 L) / 2 M
Volume of 2 M KMnO4 solution ≈ 1.25 mL

Figures and Data Points

KMnO4 Solution Concentration Density (g/L)
1 M 158.03
2 M 79.015
3 M 52.677
4 M 39.5075

Figure 1: Relationship between KMnO4 solution concentration and density.

References

  1. Pearson General Chemistry: https://www.pearson.com/channels/general-chemistry/asset/f47ae67c/the-concentration-of-a-solution-of-potassium-permanganate-kmno4-can-be-determine
  2. NCBI – Quantification of MnO4−: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9958420/
  3. PWISTA APSI Chemistry 2013: https://www.pwista.com/Microconcept%20labs/TEACHER%20VERSION%20Microscale%20Titration%20Lab%208-Day%204%20Segment%203.pdf