Polonium (Po), atomic number 84, density 9.196 g/cm³, melts at 254°C. Notably radioactive, with Po-210 (half-life 138.376 days) used in nuclear batteries and anti-static devices. Discovered by Marie Curie in 1898, it’s rare, extracted from uranium ores. Highly toxic, requires careful handling.
Basic Properties of Polonium
Property
Detail
Atomic Number
84
Atomic Mass
209 u
State at Room Temperature
Solid
Density
9.32 g/cm3
Number of electrons
84
Number of protons
84
Number of neutrons
125
Group
16
Period
6
Year Discovered
1898 by Marie Curie
Cost
~$100 per microgram due to extreme radioactivity
Physical Properties of Polonium
Property
Detail
Melting Point
254°C
Boiling Point
962°C
Solubility
Insoluble in water; soluble in acids
Electrical Conductivity
Metallic conductor
Magnetism
Very slightly paramagnetic
Color
Silvery-gray metallic
Odor
Odorless
Hardness
2.0 Mohs
Vapor Pressure
0.04 Pa at 500°C
Viscosity
N/A (solid at room temperature)
Surface Tension
N/A (solid at room temperature)
Refractive Index
N/A
Specific Heat Capacity
130 J/kg·K
Coefficient of Thermal Expansion
N/A
Chemical Properties of Polonium
Property
Detail
Reactivity
Extremely radioactive and reactive; decays to lead (Pb)
Flammability
Flammable solid in powder form
pH
N/A
Oxidation States
-2, +2, +4, +6
Electronegativity
2.0
Corrosion Resistance
None; reacts violently with many substances
Chemical Stability
Unstable; radioactive
Heat of Combustion
N/A
Reaction Rates
Decays rapidly due to radioactivity
Acid-Base Behavior
N/A
Redox Potential
N/A
Spectroscopic Properties of Polonium
Property
Detail
Absorption Wavelengths
216 nm, 256 nm
Emission Wavelengths
810 nm (alpha radiation)
NMR Properties
N/A
Polonium Crystallographic Properties
Property
Detail
Crystal Structure
Cubic
Lattice Parameter
3.35 Å
Space Group
Fm3m
Pearson Symbol
cF12
Polonium Electronic Properties
Property
Detail
Band Gap
N/A
Electrical Resistivity
10-7 ohm-meters
Polonium Isotopic Composition
Isotope
Natural Abundance (%)
Half-life
Decay Mode
Po-208
Trace
2.9 years
Alpha decay
Po-209
Synthetic
103 years
Alpha decay
Po-210
Trace
138.376 days
Alpha decay
Po-211
Synthetic
0.516 seconds
Alpha decay
Po-212
Synthetic
0.3 microseconds
Alpha decay
Po-214
Synthetic
164.3 microseconds
Alpha decay
Polonium Discovery
Property
Detail
Element Name
Polonium
Symbol
Po
Atomic Number
84
Discovered By
Marie Curie and Pierre Curie
Year of Discovery
1898
Origin of Name
Named after Poland, Marie Curie’s native country
First Isolation
Separated from uranium ore through a series of chemical processes
Interesting Facts on Polonium
Fact
Detail
Radioactivity
Polonium was the first element discovered that was radioactive without the presence of uranium.
Curie’s Discovery
Marie Curie chose the element’s name as a political statement in support of her native Poland.
Rare Element
Polonium is extremely rare in nature and is usually produced synthetically in nuclear reactors.
Heat Generation
Polonium-210 can generate temperatures up to 500°C due to its high radioactivity, which makes it useful as a compact heat source.
Toxicity
Polonium is highly toxic, with a lethal dose (LD50) for an adult of about 1 microgram if ingested.
Polonium Applications and Uses
Application Area
Description
Industrial Uses
Used as a heat source in space satellites and lunar missions due to its ability to generate heat through radioactive decay.
Medical Uses
Employed in anti-static devices in pharmaceutical labs and as a compact heat source for thermoelectric power in remote medical devices.
Agricultural Uses
Research into using polonium as a means to induce mutations in seeds for crop improvement (highly regulated).
Energy Production
Polonium-210 is considered for use in nuclear batteries (radioisotope thermoelectric generators) for deep-space missions.
Technology and Electronics
Utilized in devices that eliminate static charges in machinery and dust removal in photographic film production.
Environmental Applications
Investigated for potential use in environmental monitoring devices due to its radioactive properties enabling sensitive detection of pollutants.
Safety Precautions for Polonium
Precaution
Detail
Handling
Polonium must be handled in specialized facilities with appropriate containment to prevent exposure.
Personal Protective Equipment (PPE)
Use of gloves, protective clothing, and full-face respirators when working with polonium to prevent inhalation or ingestion.
Storage
Stored in tightly sealed containers, usually under inert atmospheres to prevent the escape of radioactive particles.
Waste Disposal
Radioactive waste containing polonium must be disposed of according to regulatory standards, involving secure containment and long-term storage.
Emergency Procedures
Facilities must have protocols for containment and decontamination in case of accidental release, including emergency showers and eye wash stations.
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