NCL3 Lewis Structure: Drawings, Hybridization, Shape, Charges, Pairs

We shall examine the ncl3 lewis structure, molecular geometry, hybridization, formal charge, and applications of nitrogen trichloride (NCl3) in this article.

NCl3 is made up of one nitrogen atom and three chlorine atoms (nitrogen trichloride). Three single bonds surround the nitrogen atom in the Lewis structure of NCl3, and three chlorine atoms are connected to it. The chlorine atom possesses three lone pairs, while the nitrogen atom has only one.

  1. How to Sketch the Lewis Structure of NCL3
  2. Molecular Geometry of Nitrogen Trichloride
  3. Hybridization in Nitrogen Trichloride
  4. NCL3 Lewis structure formal charge
  5. NCL3 Uses

Nitrogen trichloride, often known as NCl3, is a highly explosive compound that looks as an oily liquid. It has a chlorine-like odour. It possesses a 0.6 D dipole moment, indicating that it is fairly polar.

Because of the size disparity between chlorine and nitrogen in terms of size, nitrogen trichloride becomes the most deadly explosive chemical in pure concentration.

1. How to Sketch the Lewis Structure of NCL3:

The distribution of electrons around individual atoms in a structure is depicted in a Lewis diagram. NCl3 has a Lewis structure that is similar to NF3. One nitrogen atom is in the middle, with three chlorine atoms equally distributed around it.

The core atom of the NCl3 Lewis dot structure has one lone pair, whereas each chlorine atom has three.

Follow these steps to make the Lewis dot structure of NCl3.

Step 1: Count the total number of valence electrons in NCl3

To begin, the quantity of valence electrons in NCl3 must be determined. Because the valence electron aids in determining how many electrons are present in an atom’s outermost shell. Simply glance at an atom’s periodic group to determine its valence electron.

The periodic table places nitrogen in the 15th group and chlorine in the 17th. As a result, nitrogen has a valence electron of 5, while chlorine has a valence electron of 7.

Nitrogen has 5 total valence electrons.

Chlorine has 7 total valence electrons.

As a result, the total number of valence electrons accessible to draw the NCl3 leis structure is 5 + 7 × 3 = 26.

NCl3 is made up of three chlorine atoms and one nitrogen atom.

Step 2: Place the least electronegative atom in the middle

It’s now time to locate the least electronegative atom between nitrogen and chlorine and place it in the middle of Lewis’ figure. Because electronegativity atoms with fewer electrons share more electrons than terminal atoms.

Between nitrogen and chlorine, electronegativity climbs from left to right in the periodic table, making nitrogen the least electronegative atom.

Place nitrogen in the middle of the Lewis diagram, with chlorine equally placed around it.

Step 3: A single bond connects nitrogen with chlorine

To attach each chlorine atom to the centre atom, which is nitrogen at this time, we’ll use a single bond.

Simple Structure of NCl3 from wikipedia

Count how many valence electrons we’ve used so far in the structure. We employ three single bonds in the aforementioned structure because one single bond carries two electrons. We used 6 electrons out of a total of 26 valence electrons in the NCl3 Lewis structure.

20 valence electrons = (26 – 6)

We now have an additional 20 valence electrons.

Step 4: Starting with the outer atom, place the remaining valence electrons

In the Lewis diagram, we always begin by importing electrons from the outer atom. We will also arrange the leftover valence electron around the exterior atom first in this situation (chlorine).

Chlorine requires 8 electrons to complete its octet, but due to a single bond, it already has two. To complete its octet, chlorine just need 6 electrons.

As a result, each chlorine atom in the structure will have six electrons added to it.

We surrounded each chlorine atom with six electrons, as seen in the diagram above. So far, we’ve consumed 24 electrons out of a total of 26 valence electrons. And, because all of the chlorine atoms in the aforementioned configuration have eight electrons around them, they complete their octet.

However, the core atom of nitrogen still requires two electrons to complete its octet or maintain stability.

Step 5. Complete the core atom octet and, if required, employ a covalent bond

We’ve reached the end of the process for drawing the NCl3 Lewis dot structure. Now we must complete the octet of the centre atom, which is nitrogen in this example.

So, whereas nitrogen requires eight electrons to complete its octet, it only has six electrons surrounding it (3 single bonds).

As a consequence, fill the octet of nitrogen with 2 electrons from the leftover valence electrons.

Because each element (nitrogen and chlorine) is surrounded by eight electrons, they have completed their octet in the aforementioned arrangement.

So far, we’ve built the best and most stable Lewis structure for Nitrogen trichloride.

2. Molecular Geometry of Nitrogen Trichloride:

The tetratomic molecule nitrogen trichloride is made up of three chlorine atoms connected to a single nitrogen atom by one lone pair of valence electrons.

It gives nitrogen trichloride a trigonal pyramidal molecular shapeThe Valence Shell Electron Pair Repulsion Principle can be used to investigate it further.

The nitrogen trichloride is said to have a steric number of 4 and one lone pair of valence electrons. Only a trigonal pyramidal form is acceptable for both criteria.

To get the steric count, multiply the number of atoms linked to the core atom by the number of lone pairs of electrons.

The molecule’s bent conformation is also caused by the nitrogen atom’s lone pair of electrons, which lower the bond angle from 120o to 109.5o.

The lone pair of electrons exert pressure on the chlorine atoms, which is unabated since none of the chlorine atoms have lone pairs of electrons.

The distance between nitrogen and chlorine is 1.759 Å.

3. Hybridization in Nitrogen Trichloride:

Nitrogen The core atom of trichloride is nitrogen, with three chlorine atoms encircling it from three sides. As a result, the hybridization structure is AX3N, corresponding to the central atom’s sp3 hybridization. The symbol N denotes the single electron pair on the nitrogen atom.

One 2s orbital and three 2p orbitals combine to form four new hybrid orbitals with equal energy levels for the nitrogen atom.

In the excited state, two valence electrons acquire the 2s shell, which corresponds to the lone pair of valence electrons. Furthermore, three left valence electrons occupy each of the 2p shells.

The nitrogen trichloride molecule is made up of three single bonds, each of which connects nitrogen to one chlorine element.

There is no pi bond in the nitrogen trichloride molecule since single bonds can only be formed via sigma bonds.

The molecule shows sp3-sp3 head-on overlapping due to the location of orbitals in the nitrogen trichloride during the excited state.

It is the most powerful sort of bond creation because it makes the structure extremely stable and prevents the formation of bonds with any surrounding atom.

4. NCL3 Lewis structure formal charge:

A molecule’s formal charge is the charge that an atom would have if the electrons in the bonds were reallocated uniformly among the atoms. After subtracting the amount of nonbonding electrons from a neutral atom’s valence electrons, the number of bonds related to that atom in the Lewis structure is removed.

The formal charge is determined as follows:

Formal Charge = #valence shell electrons (free atom) – # lone pair electrons – 1/2 #bonding electrons


All three Cl atoms=0

5. NCL3 Uses:

  • The bleaching agent was nitrogen trichloride.
  • As an explosive, nitrogen trichloride was utilised.

Madhusudan DN

Hi....I am D N Madhusudan, I have completed my master's in General Chemistry from the University of Mysore. Apart from this, I like to read and listen to Music. Let's connect through LinkedIn:

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