15 Facts on HBr + CH3CH2OH: What, How To Balance & FAQs

HBr is an inorganic halide, and CH3CH2OH is an organic liquid. Let us explore how both of these compounds react with each other following extensive pathways. 

Hydrogen Bromide, having the chemical formula HBr, is also known as Hydrobromic acid. The compounds used to synthesize bromide compounds deliver bromine ions. Ethanol, having the chemical formula CH3CH2OH, is recognized as a renewable fuel. It reacts with Br ion to conduct a unimolecular substitution reaction.

This article is going to focus on some interesting facts about HBr + CH3CH2OH. It will stress the aspects like types of reaction, product formation, formation of conjugate pairs, etc.

What is the product of HBr and CH3CH2OH?

Ethyl Bromide (CH3CH2Br) and Water (H2O) is the two products formed when Ethanol (CH3CH2OH) reacts with Hydrogen Bromide (HBr).

CH3CH2OH+ HBr ———-> CH3CH2Br + H2O

What type of reaction is HBr + CH3CH2OH

The ethanol and hydrogen bromide (HBr) reactions are classified as nucleophilic substitution reactions.

image 1 1 1
Step 1: Protonation of ethanol
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Step 2: Nucleophilic substitution of Ethanol by Bromine

How to balance HBr + CH3CH2OH

The following steps can be considered to balance the equation HBr + CH3CH2OH.

  • Look at the unbalanced equation to make the list of elements present here.

HBr + CH3CH2OH —> CH3CH2Br+ H2O

  • The above four elements are also present on the product’s side.
  • On the reactant side, there are four elements: C, H, O & Br.
  • Now, make a list to count the moles for both the product and reactant sides.
ElementsNo of moles on reactant sideNo of moles on the product side
C22
H77
O11
Br11
Table for No of moles on reactant and product side
  • To balance chemical reactions, the stoichiometric coefficient is added generally until the mole number of all molecules is the same.
  • Here, the number of moles for every element is the same on both the product and reactant sides.
  • Therefore, the equation is already balanced, and it can be rewritten as-

HBr + CH3CH2OH = CH3CH2Br+ H2O

HBr + CH3CH2OH titration

HBr + CH3CH2OH does not participate in the Titration reaction. HBr is a halide; it does not participate in any type of titration reaction like complexometric, redox, or acid-base. 

HBr + CH3CH2OH net ionic equation

HBr + CH3CH2OH has no net ionic equation because it is not a redox reaction. 

HBr + CH3CH2OH conjugate pairs

HBr + CH3CH2OH has following conjugate pairs:

  • The conjugate pair of HBr = Br
  • The conjugate pair of CH3CH2OH= C2H5O (Ethoxide)

HBr and CH3CH2OH intermolecular forces

In HBr + CH3CH2OH, the following intermolecular forces are present.

  • CH3CH2OH shows dipole-dipole interactions between polar molecules.
  • CH3CH2OH shows low polarity dispersion forces.
  • CH3CH2OH consists H-atom thus showing hydrogen bonding.
  • HBr molecule poses strong dipole-dipole forces.
  • HBr possesses dispersion forces due to the presence of polar molecules H & Br.

HBr + CH3CH2OH reaction enthalpy

The reaction enthalpy of the first step of the HBr + CH3CH2OH reaction is positive as stable bond-breaking causes energy absorption. But, for the second step, the reaction enthalpy is negative due to release in energy for stable bond formation.

Is HBr + CH3CH2OH a buffer solution

HBr + CH3CH2OH is not a buffer solution. Although HBr is a strong acid, CH3CH2OH is not its conjugate pair. So, this mixture cannot be used to maintain Hydrogen ion concentration. 

Is HBr + CH3CH2OH a complete reaction

The reaction between HBr + CH3CH2OH is a complete reaction because the product Ethyl bromide is a stable compound.

Is HBr + CH3CH2OH an exothermic or endothermic reaction

HBr + CH3CH2OH is endothermic in the first step due to the absorption of energy from surroundings and exothermic in the second step due to the release of energy.

Is HBr + CH3CH2OH a precipitation reaction

HBr + CH3CH2OH is a precipitation reaction. The reaction produces ethyl bromide, which is a water-insoluble compound.

Is HBr + CH3CH2OH reversible or irreversible reaction

HBr + CH3CH2OH reaction is not completely reversible. Only the first step is reversible, where carbocation formation occurs from CH3CH2OH.  

Is HBr + CH3CH2OH displacement reaction

HBr + CH3CH2OH is not a displacement reaction because Br or OH is not inter- changing their position during product formation.

Conclusion                

CH3CH2OH and HBr both have wide applications for industrial purposes. CH3CH2OH is a colorless liquid readily used as engine fuel, for household heating purposes.